Lithogeochemistry of granitoids in the São Sebastião flower structure, São Paulo

Abstract

The aim of this paper is to present lithochemical data from the granitoids found between Guarujá and São Sebastião in a segment of the Costeiro Complex in São Paulo, State, Brazil. This part of the Ribeira Folded Belt is composed of para-derived rocks on the eastern side, and ortho-derived rocks on the western side of the belt, organized in a ductile shear zone forming a positive flower structure, whose axis runs ENE-WSW. Large boudins of amphibolite occur within predominant kinzigitic gneisses along this axis. The intrusive basic protoliths of the amphibolites have a 580 Ma (U-Pb SHRIMP) crystallization age. SiO2 contents of the granitoids vary between 68 and 74%, corresponding to monzogranites and granodiorites. Some outcrops display mafic enclaves of quartz-monzodiorites. The granitoids show calc-alkaline affinity while their mafic enclaves tend towards an alkaline affinity. The lower content in SiO2 coupled with coherent differences on some trace element concentrations (e.g. Zr-Hf) contribute to clearly distinguish the enclaves from their country rocks and to suggest intense chemical interaction among the materials during crystallization. The REE pattern, the depletion in Sr, P-Ti, Ta-Nb, and the distribution of the samples on the R1-R2 diagram suggest a syn-collision island arc environment for generation of these rocks.